Contents
Structure and
properties
V. V. Davydenko, A. A. Nesterov, E. V.
Lebedev
Relaxation behavior
of composition containing structurizing
filler.............................................................139
Structure
peculiarities of nanoporous carbon materials obtained
with а template
synthesis method.......143
V.D.Myshak,
E.V. Lebedev, V.I. Shtompel,S.N.Ostapiuk,V.V.Seminog
Studying
of the influence of hexamethylenetetramine on structure and properties of
secondary polythene..........................................................................................................................................................154
s.v.
riabov,
v.v. boyko, v.i. bortnitskii, t.v. dmitrieva,
l.v. kobrina, Yu.Yu. kercha
Thermal
mass-spectrometry of polyurethane compositions filled by chitosan............................................161
H.A.Sirenko, V.P.Sviderskiy, L.Ya.Midak, L.V.Karavanovich
Influence of temperature to a
creep of composite materials because of polytetraftorethilene
for
want
of by constant to a load..........................................................................................................................167
O.E. Ermolovich, A.V. Makarevich
Structure and properties of
biodegradable film materials Based on compatibilized
polyethylene – starch
compositions................................................................................................................174
R.I.
Grakovich, T.I. Alexandrova,
P.N. Grakovich
Synthesis
polymers
L.P.
Robota, N.A. Kuzmak,
O.А.
Savelyeva, T.V. Travinskaya,
Yu.V. Savelyev ,
А.V.
Rudenko
N.A.Bus’ko,
A.V.Barantsova, V.K.Grishchenko, M. Zanoaga, F.
Tanasa, E.G.Privalko, V.D.
Myshak,
V.V.
Ageeva
Synthesis
and properties of block copolymers on the base of oligomeric polyazoinitiator
and
butylmethacrylate.....................................................................................................................................194
Medecine
polymers
N.A. Galatenko, N.L. Zbanatskaya, L.Yu. Nechaeva, V.P. Gritsenko
Study of
properties of
composition for osteoplastic
with decamethoxine................................................202
Polymer journal,
№3, 2005
Abstracts
Relaxation
behavior of composition containing structurizing
filler
V. V. Davydenko, A. A. Nesterov, E. V.
Lebedev
Institute of
Macromolecular Chemistry NAS of
48, Kharkivske shausse, 02160,
Relaxation
properties of the polyurethane filled with structurizing filler have been studied. It was shown that
the systems containing structurizing filler possess
anomalous properties in the concentration range corresponding the concentration of polyurethane nano-hybrid network formation.
Structure peculiarities of
nanoporous carbon materials obtained with
а template synthesis
method
Yu.P.Gomza1,
L.V.Golovko2, V.V. Shilov1 ,
S.D.Nesin1, V.A.Povazhny2,
A.G.Terentyev3
1Institute of Macromolecular
Chemistry, NAS of
48 Kharkivske shausse, Kyiv, 02160
2Institute of Bioorganic
Chemistry and Petrochemistry, NAS of
50 Kharkivske shausse, Kyiv, 02160
3Institute of Molecular Biology
and Genetics, NAS of
150 Ak. Zabolotny str., Kyiv, 03143
Methods of small
and wide angles X-ray scattering features the evolution of short-range ordering
and роrosity of nanopore carbon adsorbents obtained with а template synthesis method at
all intermediate stages carbon retorts forming, and also their some modified
forms produced with а grafting various organic
compounds to а carbon surface
were investigated.. It was established that process inner surface nanopore modifying leads to mean nanopore diameter lowering and is асcompanied decreasing amount
primary nanopores entering to mass-fractal
aggregates.
Studying of the influence of
hexamethylenetetramine on structure and properties of secondary
polythene
V.D.Myshak, E.V.Lebedev, V.I.Shtompel, S.N.Ostapiuk, V.V.Seminog
For the first time
the influence of small impurity hexamethylenetetramine on properties of
compositions is investigated on the basis of secondary polythene. Structural
characteristics with the help of methods of ИК-spectroscopy,
рентгеноструктурного the analysis, physicomechanical property are investigated, researches by
definition of the maintenance of gel – fraction.
Thermal
mass-spectrometry of polyurethane compositions filled by chitosan
s.v.
riabov,
v.v. boyko, v.i. bortnitskii, t.v. dmitrieva,
l.v. kobrina, Yu.Yu. kercha
Institute
of Macromolecular Chemistry NAS of
Ukraine,
02160, Kiev-160, Kharkivs’ke shosse, 48
Thermal
mass-spectrometry (TMS) has been employed to investigate processes of thermal
destruction of segmented polyurethane and it’s
compositions filled by chitosan. The features of
thermal destruction for segmented polyurethane and related compositions before
and after their storage in a soil have been determined. Application of TMS is
shown to permit the processes of biodegradation of polymeric materials to
investigate.
Influence of
temperature to a creep of composite materials because of polytetraftorethilene
for want of by constant to a load
H.A.Sirenko1,
V.P.Sviderskiy2, L.Ya.Midak1,
L.V.Karavanovich1
57,
str. Shevchenka, 76000,
2Khmelnitsky
11, str. Institutska, 29000,
The creep of
composite materials because of polytetraftorethilene,
filled filamentary and powder fillers, for want of increased temperatures and
constants loads is investigated. Is established, that the
increase of a resistance to a load of a polymeric material in a specific
direction is possible to reach it by preceding
deformation.
Structure and properties of
biodegradable film materials Based on compatibilized
polyethylene – starch compositions
O.E. Ermolovich, A.V. Makarevich
V.A. Belyi Metal-Polymer Research Institute of
NASB
32a,
The structure of
composite films made of blends of polyethylene and glycerin-plasticized starch
or the blends compatibilized by a fund ionalized polyethylene with grafted itaconic acid has been studied by the IR spectroscopy of
MDTIR, AFM and SEM at the molecular, nano- and microlevels. Structural variations proceeding at compatibilization of the film composites were attributed to
intensified physi co-chemical interactions at the
interfaces and arising chemical bonds het\veen the
functional groups in starch, glycerin and compatibilizing agent. Improved homogeneity and healing of
defects in the film structure in the presence of the compatibilizer ameliorates their deformation, strength and
biodegradabilily
characteristics.
R.I. Grakovich1,
T.I. Alexandrova2, P.N.
Grakovich1
1V.A. Belyi Metal-Polymer Research Institute of
NASB
2P.O.
October Ave. 48, 246000,
The effect of UV
radiation on the magnitude of 3D stresses in composites has been investigated.
Thermo-fatigue processes in PE samples have been studied as dependent on their
formation regimes. The obtained experimental data can be used for forecasting
durability of polymer composites under the effect of atmospheric
factors.
Biodeterioration
and fungistaticity of polyurethanes modified with
metal compounds
L.P.
Robota1, N.A. Kuzmak1,
O.А.
Savelyeva1, T.V. Travinskaya1, Yu.V. Savelyev1 ,
А.V.
Rudenko2
1Іnstitute
of Macromolecular Chemistry NAS of
48,
2Іnstitute
of
9а,
Yu.
Kotsubinskogo, 03053, Kyiv-53,
The
degree of biodeterioration of branched polyurethanes,
modified with inorganic and metal-organic additives, as well as the level of
their fungistatic properties in comparison with linear
polyurethanes has been staudied. Polymers of both
branched and linear structures display the fungistatic
properties.
Synthesis
and properties of block copolymers on the base of oligomeric polyazoinitiator and
butylmethacrylate
N.A.Bus’ko1,
A.V.Barantsova1, V.K.Grishchenko1, M. Zanoaga2,
F. Tanasa2, E.G.Privalko1, V.D. Myshak1,
V.V. Ageeva1
1Institute
of Macromolecular Chemistry NAS of
48,
2Institute
of Macromolecular Chemistry of
The
processes of synthesis and properties of threeblock
and polyblock copolymers obtained on the base of copolyamide and diene rubber have
been investigated. The structure of synthesized block
copolymers were confirmed by the IR- and 1Н
NMR - spectrooscopy
methods. Their physico-chemical and physico-mechanical characteristics have been
studied.
Study of
properties of
composition for osteoplastic
with decamethoxine
N.A. Galatenko, N.L. Zbanatskaya, L.Yu. Nechaeva, V.P. Gritsenko
Institute of
Macromolecular Chemistry, NAS of
48,
Investigations
of composition
for osteoplastic with antiseptic action by IR-spectroscopy and
photometry methods, cohesive strength testing were.